Preheat oven to 350°F. Prepare a 9x12” pan with baking spray and parchment. In a large mixing bowl, add the flour, baking soda, baking powder, and salt. Whisk together to combine. Set aside.
In another large bowl, add eggs, sugar, sour cream, vegetable oil, and vanilla. Whisk together until smooth and well combined.
In a small mixing bowl or 2-cup liquid measuring cup, add the hot coffee and cocoa powder. Whisk together until well-combined and smooth. Allow to sit for 2 minutes, then add the cocoa mixture into the mixing bowl with the wet ingredients (eggs, sour cream, etc.), then mix until smooth.
Add the wet ingredients into the bowl with the dry ingredients, and mix until smooth. Pour the cake batter into the prepared pan, and bake for 30 to 35 minutes or until an inserted toothpick comes out clean. Allow to cool completely before frosting.